You cannot Instance this class with Instance.new()

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Properties

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PlayerCount: int

The PlayerCount holds a int value which has the total number of players in the game server

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RespawnTime: int

The property holds a int value which is number of seconds to spawn player after players death. This is read only for client sided scripts and can be changed by server sided scripts.

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Functions

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GetPlayer(string username)

GetPlayer will return a Player type. An example: 
local Players = Game:GetService("Players")
local cubern_player = Players:GetPlayer("Cubern")
cubern_player:Kick("Yoink!")
-- Cubern currently doesnt support getting players like Players["Cubern"]

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GetLocalPlayer()

Returns localPlayer as a Player type. This function can only be called by client-sided scripts. An example: 
local Players = Game:GetService("Players")
local localPlayer = Players:GetLocalPlayer()
printl(localPlayer.username)

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Signals

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OnPlayerEntered

The signal is called when a new player joins the game. This is valid on both: client sided and server sided scripts. An example: 
local Players = Game:GetService("Players")
local ChatService = Game:GetService("ChatService")
Players:Connect("OnPlayerEntered", __SCRIPT__, "FunctionToCall")

function FunctionToCall(Player)
    ChatService:Push("Everybody! Welcome: " .. Player.username);
end

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OnPlayerLeft

The signal is called when a player leaves the game. This is valid on both: client sided and server sided scripts. An example: 
local Players = Game:GetService("Players")
local ChatService = Game:GetService("ChatService")
Players:Connect("OnPlayerLeft", __SCRIPT__, "FunctionToCall")

function FunctionToCall(Player)
    ChatService:Push("Goodbye " .. Player.username .. "! We hope to see you again!");
end